|本期目录/Table of Contents|

[1]雪峰.纤维用ATO@TiO2导电晶须的制备及其性能研究郭雪峰[J].丝绸,2021,58(2):021102.
 GUO Xuefeng.Preparation and Properties of Conductive ATO@TiO2 Whiskers Used in Fiber[J].Journal of Silk,2021,58(2):021102.
点击复制

纤维用ATO@TiO2导电晶须的制备及其性能研究郭雪峰(PDF)

《丝绸》[ISSN:1001-7003/CN:33-1122/TS]

卷:
58
期数:
2021年2期
页码:
021102
栏目:
研究与技术
出版日期:
2021-02-20

文章信息/Info

Title:
Preparation and Properties of Conductive ATO@TiO2 Whiskers Used in Fiber
文章编号:
1001-7003(2021)02-0000-00
作者:
雪峰
常州纺织服装职业技术学院 纺织学院,江苏 常州 213164
Author(s):
GUO Xuefeng
School of Textile, Changzhou Vocational Institute of Textile and Garment, Changzhou 213164, China
关键词:
二氧化钛锑掺杂氧化锡包覆表面电阻率导电晶须
Keywords:
Titanium dioxide Sb doped SnO2 coating surface resistivity conductive whisker
分类号:
TS102.528.5;TQ134.11
doi:
-
文献标志码:
A
摘要:
ATO(锑掺杂氧化锡)是一种具有高导电性、颜色浅、耐热性好等优点的透明导电氧化物(TCO),包覆TiO2后可以作为导电填料共混纺丝制成导电纤维,在纺织行业应用前景广阔。以乙酰丙酮为螯合剂,氯化锡锑为原料,在TiO2晶须表面包覆ATO,制备了浅蓝色的ATO@TiO2导电晶须,该方法条件温和,成本低廉,避免了大量酸碱的消耗,具有大规模生产应用的潜力。文章探讨了包覆比,掺杂比,煅烧温度,乙酰丙酮与金属氯化物摩尔比对ATO@TiO2导电晶须导电性能的影响。结果表明,包覆比为45%、掺杂比为9%、乙酰丙酮与金属氯化物摩尔比为6、煅烧温度为500 ℃时,导电晶须的表面电阻率优化值为6.32 kΩ·cm。
Abstract:
ATO (antimony doped tin oxide) is a kind of transparent conductive oxide (TCO) with high electrical conductivity, light color and good thermal stability, etc. After being coated with TiO2, it can be used as conductive filler and made into conductive fiber by blended spinning. It is a kind of material with high conductivity and wide application in textile industry. Light blue c onductive ATO@TiO2 whiskers were prepared by using acetylacetone as chelating agent, antimony tin chloride as raw material and coating TiO2 whiskers with ATO. This method has the advantages of mild conditions, low cost, and less consumption of acid-base than coprecipitation method. It has the potential of mass production and application . The effects of coating ratio, doping ratio, calcination temperature and molar ratio of acetylacetone to metal chloride on whisker conductivity were investigated by single factor test. The results show that the optimal value of the surface resistivity of conductive whiskers was 6.32 kΩ·cm at the synthesization condition of a coated ratio of 45%, a doping ratio of 9%, a molar ratio of acetylacetone to metal chloride of 6, and a calcination temperature of 500℃.

参考文献/References:

[1] ZENG Wei, SHU Lin, LI Qiao, et al. Fiber-based wearable electronics: a review of materials, fabrication, devices, and applications[J]. Advanced Materials, 2014, 26(31): 5310-5336.
[2]张忠峰,王克俭. 电磁屏蔽及抗静电包装塑料及应用[J]. 塑料包装, 2019, 29(3): 1-5.
ZHANG Zhongfeng, WANG Kejian. Electromagnetic shielding and antistatic packaging plastics and their applications[J]. Plastics Packaging, 2019, 29(3): 1-5.
[3]叶凤林,王海兴,崔丽荣. 抗静电剂在玻璃纤维生产中的应用[J]. 化工管理, 2019(21): 186-187.
YE Fenglin, WANG Haixing, CUI Lirong. The applications of antistatic agent on the production of glass fiber[J]. Chemical Enterprise Management, 2019(21): 186-187.
[4] WANG Mingxu, GAO Qiang, DUAN Hao, et al. Scalable synthesis of high-purity TiO2 whiskers via ion exchange method enables versatile applications[J]. RSC Advances, 2019, 9(41): 23735-23743.
[5]王鹏,张瑜,陈彦模. 复合型导电纤维的制备及其开发现状[J]. 合成纤维, 2004, 33(S1): 18-20.
WANG Peng, ZHANG Yu, CHEN Yanmu. The development and preparation of composite electrically conductive fiber[J]. Synthetic Fiber in China, 2004, 33(S1): 18-20.
[6]王怡,王春晓,王首华,等. 纳米ATO透明隔热涂料的制备与性能研究[J]. 涂料工业, 2019, 49(10): 43-47.
WANG Yi, WANG Chunxiao, WANG Shouhua, et al. Preparation and properties of nano ATO transparent thermal insulation coatings[J]. Paint and Coating Industry, 2019, 49(10): 43-47.
[7]王靓,赵石林. 纳米氧化锡锑透明隔热涂料的制备及性能研究[J]. 涂料工业, 2004, 34(10): 4-8.
WANG Liang, ZHAO Shilin. Study on preparation and performance of nano antimony tin oxide(ATO) based transparent heat insulation coatings[J]. Paint and Coating Industry, 2004, 34(10): 4-8.
[8] ZHANG Jianrong, GAO Lian. Synthesis and characterization of antimony-doped tin oxide(ATO) nanoparticles[J]. Inorganic Chemistry Communications, 2004, 7(1): 91-93.
[9] M?LLER V, RASP M, S?TEFANIC G, et al. Highly conducting nanosized monodispersed antimony-doped tin oxide particles synthesized via nonaqueous sol-gel procedure[J]. Chemistry of Materials, 2009, 21(21): 5229-5236.
[10] MOHAMMED M R, JAHIR A, ABDULLAH M, et al. Development of creatine sensor based on antimony-doped tin oxide (ATO) nanoparticles[J]. Sensors & Actuators: B Chemical, 2017:242.
[11] WANG Lianzhou, SASAKI T. Titanium oxide nanosheets: graphene analogues with versatile functionalities[J]. Chemical Reviews, 2014, 114(19): 9455-9486.
[12]李大玉,张文韬,张超. 不同种类金属掺杂改性TiO 2材料光催化性能的研究进展[J]. 材料导报, 2019, 33(23): 3900-3907.
LI Dayu, ZHANG Wentao, ZHANG Chao. Research progress in improving the photocatalytic properties of TiO2 materials by doping different metals[J]. Materials Reprots, 2019, 33(23): 3900-3907.
[13]刘于民. 二氧化钛表面功能化及应用研究[D]. 镇江: 江苏大学, 2011.
LIU Yumin. Surface Functionalization of TiO2 and the Application[D]. Zhejiang: Jiangsu University, 2011.
[14] WANG Yanli, ZHANG Shenhua, WANG Ping, et al. Synthesis and corrosion protection of Nb doped TiO2 nanopowders modified polyaniline coating on 316 stainless steel bipolar plates for proton-exchange membrane fuel cells[J]. Progress in Organic Coatings, 2019, 137 : 105327.
[15] LIU Xinghua, ZHAO Lijiang, WANG Shitong, et al. Hierarchical-structure anatase TiO2 with conductive network for high-rate and high-loading lithium-ion battery[J]. Science Bulletin, 2019, 64(16): 1148-1151.
[16]刘婉婉. 纤维用浅色ATO@TiO2导电晶须的制备及性能研究[D]. 无锡: 江南大学, 2018.
LIU Wanwan. Preparation and Properties of Fiber Used Conductive ATO@TiO2 Whisker with Light Color[D]. Wuxi: Jiangnan University, 2018.
[17]王少伟. 改性二氧化钛/PA6导电纤维的制备及其性能研究[D]. 无锡: 江南大学, 2013.
WANG Shaowei. Preparation and Properties of Modificated Titanium Dioxide/PA6 Conductive Fiber[D]. Wuxi: Jiangnan University, 2013.
[18]高强,马慧,刘婉婉,等. 导电ATO@TiO2纳米晶须的制备工艺优化研究[J]. 化工新型材料, 2016, 44(9): 81-83.
GAO Qiang, MA Hui, LIU Wanwan et al. Process optimization of electroconductive ATO@TiO2 nano whisker[J]. New Chemical Materials, 2016, 44(9): 81-83.
[19]田浩,古文全,聂登攀,等. ATO/CaSO4复合导电粉制备的研究[J]. 化工新型材料, 2012, 40(10): 99-101.
TIAN Hao, GU Wenquan, NIE Dengpan, et al. Preparation research of ATO/CaSO4 composite conductive powders[J]. New Chemical Materials, 2012, 40(10): 99-101.
[20]钱建华,刘娇,许家胜,等. 不同粒径TiO2包覆氧化锡锑后的导电性研究[J]. 功能材料, 2017,48(2): 2013-2019.
QIAN Jianhua, LIU Jiao, XU Jiasheng, et al. The conductivity research of different particle sizes of titanium dioxide coated antimony tin oxide[J]. Journal of Functional Materials, 2017, 48(2): 2013-2019.
[21] GALAVIZ-PEREZ, J.A, CHEN Fei, SHEN Qiang, et al. Enhancement and optimization of ATO nano-crystalline films properties by the addition of acetylacetone as modifier in the sol-gel process[J]. Journal of Wuhan University of Technology-Materials Science Edition,2015,30(5): 873-881.
[22] LIU Wanwan, WANG Yangyi, GE Mingqiao, et al. One-dimensional light-colored conductive antimony-doped tin oxide@TiO2 whiskers: synthesis and applications [J]. Journal of Materials Science: Materials in Electronics, 2018, 29(1), 619-627.
[23]王英. 掺锑氧化锡导电复合材料的性能研究[D]. 天津: 天津大学, 2014.

备注/Memo

备注/Memo:
基金项目:江苏省自然科学基金面上项目(BK20191165)
收稿日期:2020-07-24
作者简介:郭雪峰(1978—),女,副教授,博士,主要从事功能性纤维材料及其制品的研究
更新日期/Last Update: 2021-01-13